LOW–VALENT ORGANOMETALLIC DERIVATIVES OF PALLADIUM (0), PLATINUM (0), RHODIUM (I) AND IRIDIUM (I) WITH AMMONIUM SALT OF  THIOGLYCOLIC ACID

R.N. PANDEY; RAKESH RANJAN

Low–valent Organometallic Derivatives Of Palladium (0), Platinum (0), Rhodium (i) And Iridium (i) With Ammonium Salt Of Thioglycolic Acid, IJSR - International Journal of Scientific Research(IJSR), IJSR | World Wide Journals

Volume : IV, Issue : VIII, August - 2015

LOW–VALENT ORGANOMETALLIC DERIVATIVES OF PALLADIUM (0), PLATINUM (0), RHODIUM (I) AND IRIDIUM (I) WITH AMMONIUM SALT OF THIOGLYCOLIC ACID

R. N. Pandey, Rakesh Ranjan

Abstract :

Palladium (0), Platinum (0), Rhodium (I) and Iridium (I) derivatives of triphenyl phosphine ligated by ammonium salt of thioglycolic acid are prepared, characterized and structure are deduced using elemental analysis, magnetic moment, conductance, IR, UV–vis and 1H NMR spectral data. The unionised and uncoordinated free –COONH4 group is present and bonding occurs through thiol sulphur.